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5. Conclusions

In this paper, July 1994 extratropical total ozone field is comprehensively explored over time scales ranging from monthly to synoptic. The structure of stationary ozone field shows a clear signature of wave number 1 at middle-to-high latitudes with a minimum well above the climatological mean over southern SA. This minimum seems to be related to enhanced stationary atmospheric activity over the region, as well as to a subpolar jet maximum displaced westward over the southern Atlantic. For middle to low latitudes (up to 25ºS) ozone stationary fluctuations are determined by "tropopause effect".

Transient ozone fluctuations were also analysed in relation with upper-tropospheric wave activity. Mayor zones of standard deviation of ozone daily perturbations are shown to coincide with the regions of maximum standard deviation of 300-hPa geopotential height perturbations, although the former usually attain their maximum slightly poleward and downstream. In particular, southern SA display a maximum of both ozone and geopotential height standard deviation in association with the presence of a quasi-stationary, equivalent-barotropic ridge centered near 55ºS, 90ºW.

During July 7th to 10th a transient ozone wave evolving along subpolar jet latitudes was modulated and maintained by atmospheric activity. In order to determine the relative dynamical contributions from atmospheric waves to ozone distribution two approaches were pursued. Firstly, ozone local daily changes were explained in terms of a simple ozone transport equation and by use of the mapping technique. This approach yielded results that although overestimate local ozone changes, were able to reproduce comparable spatial patterns. The second approach proposed a multivariate linear regression model that relates ozone content to tropopause pressure and potential vorticity on isentropic surfaces. Results suggested that these quantities are valid predictors for ozone field; the most important contribution given by the potential vorticity on 315ºK and by tropopause pressure.


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